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混合扩链剂对聚氨酯弹性体氢键和阻尼性能的影响
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Effect of Mixed Chain Extender on Hydrogen Bond and Damping Properties of Polyurethane Elastomer
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    摘要:

    针对纯3,3′-二氯-4,4′-二氨基二苯甲烷(MOCA)扩链制备的2,4-甲苯二异氰酸酯(TDI)型聚氨酯(PU)弹性体阻尼性能欠佳的问题,采用MOCA/聚四氢呋喃醚二醇(PTMG)混合扩链剂,通过预聚体法制备不同扩链剂比例的PTMG-TDI型PU弹性体. 分别采用FTIR、DSC、DMA测试发现:随着混合扩链剂中PTMG1000(Mn为1 000)比例增加,PU的氢键化指数降低,软硬段的微观相分离程度下降,硬段微晶的熔融温度和熔融焓随之减小,损耗因子增大. 当MOCA与PTMG1000的摩尔比为85 15时,PU硬度为85 A,拉伸强度、撕裂强度分别为33.1 MPa和70.5 kN/m,与纯MOCA制备的PU相比,硬度下降5 A,力学强度保持在较高值,损耗因子tan δ增加,制备的金属轮毂/PU复合滚轮达到耐久性检测标准,运行噪声降低3 dB.

    Abstract:

    Aiming at the problem of poor damping performance of di-phenylmethane diisocyanate (TDI) polyurethane (PU) elastomer prepared by chain extension of pure 3,3'-dichloro-4,4'-diaminodiphenylmethane (MOCA), MOCA/polytetrahydrofuran ether glycol (PTMG) mixed chain extender was used to prepare PTMG-TDI PU elastomer with different chain extender ratios by prepolymer method. FTIR, DSC, and DMA tests showed that with the increase of PTMG1000 (Mn=1 000) in the mixed chain extender, the hydrogen bonding index of PU reduced, and the microphase separation degree of soft and hard segments decreased leading to the melting temperature and melting enthalpy of hard segment microcrystalline decreased, and the loss factor tan δ increased. When the MOCA/PTMG1000 (molar ratio) is 85 15,the PU hardness, tensile strength,and tear strength are 85 A,33.1 MPa, and 70.5 kN/m, respectively. Compared with the PU prepared by pure MOCA,the hardness is reduced by 5 A, the mechanical strength is maintained at a higher value and the tan δ is increased. Finally, the prepared metal hub/PU roller meets the durability test standard, and the operating noise is reduced by 3 dB.

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易玉华 ?,陈智兴.混合扩链剂对聚氨酯弹性体氢键和阻尼性能的影响[J].湖南大学学报:自然科学版,2022,49(12):142~147

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  • 在线发布日期: 2023-01-02
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