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电解锰渣固废制备建筑保温材料实验研究
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Experimental Study on the Preparation of Building Insulation Materials Using Electrolytic Manganese Residue Solid Waste
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    针对当前电解锰渣固废的资源化利用不足、工艺复杂、经济附加值较低等问题,为有效消纳和利用电解锰渣,在前期理论分析基础上采用实验的方法,研究了基础原料配比(电解锰渣的质量与电解锰渣及粉煤灰的质量和之比)、碱激发剂配比(水玻璃、氢氧化钠和混合水的用量配比)、发泡剂和稳泡剂的种类与用量等因素对目标保温材料性能的影响. 结果表明:基础原料配比和碱激发剂配比均会对SiO2/Al2O3摩尔比、SiO2/Na2O摩尔比和水灰比产生影响,进而影响试样的力学性能;基础原料配比为0.7、SiO2/Al2O3摩尔比为4.0、SiO2/Na2O摩尔比为2.5、水灰比为0.5时建筑结构材料试样的力学性能最优,其抗压强度为11.15 MPa,密度为 1 476 kg/m3;发泡剂和稳泡剂的种类与用量会对试样的各项性能产生影响,当发泡剂为双氧水,用量为4~6 g,稳泡剂为实验室自制稳泡剂,用量为2 g时,建筑保温材料试样的各项性能最优,其导热系数为0.104~0.131 W/(m·K),抗压强度为0.69~1.49 MPa,密度为433~533 kg/m3,成本为1 294~1 722 元/m3. 该研究为较大量消纳和利用电解锰渣提供了新思路,在满足保温隔热性能的同时降低建筑能源需求,经进一步优化后具有一定的工程应用价值.

    Abstract:

    To address the issues of inadequate resource utilization, complex processes, and low economic added value associated with electrolytic manganese residue (EMR) solid waste, in order to effectively consume and utilize EMR, this study utilizes experimental methods, underpinned by preliminary theoretical analysis, to examine the impacts of basic raw material ratios (mass ratio of EMR to the combined mass of EMR and FA), alkaline activator ratios (proportions of water glass, NaOH, and mixed water), and the types and quantities of foaming and stabilizing agents on the performance of the targeted insulation material. The findings indicate that both the basic raw material ratio and the alkaline activator ratio profoundly affect the molar ratios of SiO2/Al2O3, SiO2/Na2O, and liquid/solid mass ratio, significantly influencing the mechanical properties of the samples. Optimal mechanical performance of the construction material samples is achieved with a basic raw material ratio of 0.7, a SiO2/Al2O3 molar ratio of 4.0, a SiO2/Na2O molar ratio of 2.5, and a liquid/solid mass ratio of 0.5, resulting in a compressive strength of 11.15 MPa and a density of 1 476 kg/m3. Furthermore, the type and quantity of foaming and stabilizing agents influence the sample properties significantly; optimal performance of the building insulation material samples occurs when using hydrogen peroxide as the foaming agent (4~6 g) and a laboratory-made stabilizing agent (2 g), achieving a thermal conductivity of 0.104~0.131 W/(m·K), compressive strength of 0.69~1.49 MPa, density of 433~533 kg/m3, and a cost of 1 294~1 722 CNY/m3. This study offers new perspectives on the extensive consumption and utilization of EMR, reducing building energy requirements while fulfilling insulation and thermal resistance needs, with considerable potential for engineering applications after further optimization.

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李洪强 ?,陈治平 ,钱想想 ,蔡澄汉 ,刘甜甜 ,彭逸喆 ,刘丽芳 .电解锰渣固废制备建筑保温材料实验研究[J].湖南大学学报:自然科学版,2025,52(9):174~188

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  • 在线发布日期: 2025-10-09
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