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固废制备新型建筑保温材料实验研究
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Experimental Study on Novel Building Insulation Materials Prepared from Solid Waste
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    针对固体废弃物资源化利用中存在的消纳量小、成本较高、工艺复杂等问题,提出一种消纳量大、成本较低、工艺简单的建筑保温材料制备方案. 该方案以电解锰渣和粉煤灰两种固体废弃物作为硅铝酸盐原料,以水玻璃作为碱激发剂,采用双氧水发泡工艺,制备出保温、力学性能优异,且成本较低的材料. 结果表明,水玻璃用量在一定范围内材料可以制备成型,且能够有效稳泡. 电解锰渣的掺入量范围为0%~60%,推荐掺入量为30%,最高掺入量为60%. 当电解锰渣掺入量为30%、水玻璃用量为355.4~465.4 g、双氧水用量为8 g、稳泡剂用量为2 g时,导热系数为0.084~0.093 W·m-1·K-1,抗压强度为0.92~1.43 MPa,密度为457~475 kg·m-3,制备每立方米新型保温材料所需原料成本约为750 元. 与采用偏高岭土作为前驱材料,氢氧化钠和水玻璃作为碱激发剂的同类保温材料相比,新型建筑保温材料成本仅为其24%左右. 此外,该新型建筑保温材料毒液浸出浓度低,对重金属有良好的固化作用.

    Abstract:

    In addressing the challenges of low utilization, high costs, and complex processes in solid waste recycling, a novel plan for preparing building insulation material is developed. This strategy employs electrolytic manganese residue (EMR) and fly ash (FA) as silicate materials, uses water glass (WG) as an alkaline activator, and incorporates a hydrogen peroxide foaming technique to produce insulation materials with superior mechanical properties at reduced costs. The findings reveal that WG effectively molds the material and stabilizes the foam within a certain usage range. The acceptable incorporation ranges for EMR spans from 0% to 60%, with an optimal addition of 30% and a ceiling of 60%. At 30% EMR, with 355.4~465.4 g of WG, 8 g of hydrogen peroxide, and 2 g of stabilizing agent, the material exhibits thermal conductivity from 0.084 to 0.093 W·m-1·K-1, compressive strength from 0.92 to 1.43 MPa, and density from 457 to 475 kg·m-3. The cost for the precursor materials per cubic meter of this innovative insulation material is roughly 750¥. The cost of this new material is approximately 24% of that of conventional materials using kaolinite as the precursor material and sodium hydroxide with WG as activators. Furthermore, this insulation material demonstrates low toxic leachate concentrations and effectively immobilizes heavy metals.

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李洪强 ?,彭逸喆 ,陈治平 ,刘丽芳 ,钱想想 ,蔡澄汉 ,赵岩志 .固废制备新型建筑保温材料实验研究[J].湖南大学学报:自然科学版,2025,52(11):164~177

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  • 在线发布日期: 2025-12-09
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