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连续水热转化甘油为乳酸的研究
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Research on Continuous Hydrothermal Conversion of Glycerin into Lactic Acid
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    为实现由甘油生产乳酸,开发了一套连续水热反应装置,并利用该装置对甘油水热转化为乳酸这一反应的连续过程进行研究.在300 ℃,10 MPa,NaOH 1.250 mol?L-1和碱性水热条件下,反应60 min后,成功实现了水热转化甘油为乳酸并达到近似于间歇式实验的乳酸生成率.实验结果表明,与间歇式实验结果不同,在较高碱浓度下延长反应时间导致乳酸生成率降低;同时,低分子有机酸大量生成,从而显著降低了乳酸生成选择性,这可能与连续热水反应器中的反应管具有较大的比表面积促进了乳酸进一步分解有关.基于实验结果,对该装置提出了更换反应管材质、保护反应管预热段以及两阶段供碱等改进的建议.

    Abstract:

    To realize the production of lactic acid from glycerin, a continuous hydrothermal reaction apparatus was established, and the process for continuous hydrothermal conversion of glycerin into lactic acid was studied. A yield of lactic acid approaching to that using a batch reactor could be steadily achieved under the hydrothermal conditions of 300 ℃, 10 MPa, 1.250 mol?L-1 NaOH and continuous run of 60 min. The results also showed that, with higher alkali concentration, the yields of lactic acid decreased with reaction time, which differed from the previous results using batch reactor, and that a large amount of organic acids of small weight molecule was produced abundantly, which reduced the production selectivity of lactic acid. The results were probably related to the massive specific surface area of the reactor in the continuous hydrothermal reaction apparatus, which further promoted the decomposition of the lactic acid produced. Based on the analysis of experiment results, several suggestions on the modification of the continuous hydrothermal reaction apparatus, such as the substituting material of the reactor, the protecting preheating section of the reactor and supplying alkali twice, were put forward.

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张光义,金放鸣,曾 旭,曹江林,吴 冰.连续水热转化甘油为乳酸的研究[J].湖南大学学报:自然科学版,2010,37(7):61~66

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