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基于DSC的隔震支座用橡胶材料低温结晶试验
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Experimental Study on Low Temperature Crystallization of Rubber Material for Isolation Bearing Based on DSC
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    摘要:

    为分析低温下橡胶隔震支座的性能劣化机理,对无应变状态下我国隔震支座所用橡胶材料的低温结晶性能开展了试验研究.采用差示扫描量热法(differential scanning calori- metry, DSC),对两家典型企业用于生产隔震支座的天然硫化橡胶开展了玻璃化转变温度和等温结晶熔融试验. 结果表明:无应变状态下,随着在低温下保持时间的延长,隔震支座的结晶度会逐渐增大;且受产地、生长环境及硫化工艺等不同因素的影响,不同硫化天然橡胶的结晶性能不同;仅环境温度低于-60 ℃时,用于本文研究的橡胶材料所生产的橡胶隔震支座才会丧失工程实用价值. 考虑到实际服役过程中隔震支座会受低温和应变的双重作用,本文研究成果可为揭示其低温下力学性能劣化机理、理解力学行为提供参考和依据.

    Abstract:

    To analyze the deterioration mechanism of rubber isolation bearings at low temperatures, the low temperature crystallization properties of rubber materials used for isolation bearings in China under no-strain conditions were investigated. Differential scanning calorimetry (DSC) was used to investigate the glass transition temperature and isothermal crystallization melting of natural vulcanized rubber used for the production of isolation bearings by two typical enterprises in China. The results show that the crystallinity of the isolation bearing increases with the extension of the holding time at low temperatures without strain. Additionally, the crystallization properties of different vulcanized natural rubbers are different due to various factors such as origin, growing environment, and vulcanization process. Only when the ambient temperature is below -60 ℃ the rubber isolation bearings produced by the materials used in this study lose their practical engineering value. In the actual service process, the isolation bearing is affected by the dual factors of low temperature and strain. The research results in this paper provide a reference and basis for revealing the deterioration mechanism of the mechanical properties of the isolation bearing at low temperatures and enhance our understanding of the mechanical behavior of the rubber isolation bearing at low temperatures.

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杜永峰 ,王光环 ?,李元 ,张超 .基于DSC的隔震支座用橡胶材料低温结晶试验[J].湖南大学学报:自然科学版,2025,52(5):185~194

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  • 在线发布日期: 2025-06-09
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