Epoxy resin was used as the reductant and solid-state reaction was applied to synthesize Li3V2(PO4)3 cathode for lithium batteries. The crystal structure and morphology of the sample were characterized through X-ray diffraction analysis and with scanning electron microscopy. Galvanostatic charge-discharge and cyclic voltammetry were utilized to determine the electrochemical properties of the sample. The results have shown that the synthesized Li3V2(PO4)3 possess a well-developed monoclinic crystallite structure. Its particles distribute uniformly and the size is small. The initial discharge capacity is 126.9 mAh/g at the 0.2 C rate in the voltage range of 3.0~ 4.3 V. The discharge capacity is 126.0 mAh/g and the capacity retention rate is 99.29% after 30 cycles.